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catena-poly[[(acetonitrile-N)dichlorocopper(II)]-mu-2,5-dimethylpyrazine-kappa2N:N']
1Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstrasse 40, D-24098 Kiel, Germany. cnaether@ac.uni-kiel.de
Acta Crystallographica. Section C, Crystal Structure Communications
|December 12, 2001
Abstract:
In the structure of the title compound, [CuCl2(C2H3N)(C6H8N2)], each Cu2+ cation is surrounded by two 2,5-dimethylpyrazine ligands, one acetonitrile ligand and two Cl- anions within a distorted tetragonal pyramid. The acetonitrile ligand, which forms the apex of the pyramid, the Cu2+ cation and the Cl- anions are all located in general positions, whereas each of the 2,5-dimethylpyrazine ligands is located about a centre of inversion. The 2,5-dimethylpyrazine ligands connect the Cu2+ cations via mu-N:N' coordination to form chains.