Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Bis(melaminium) sulfate dihydrate.

J Janczak1, G J Perpétuo

  • 1Departamento de Química, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, CEP 31270-901 Belo Horizonte - MG, Brazil. jjanek@dedalus.lcc.ufmg.br

Acta Crystallographica. Section C, Crystal Structure Communications
|December 12, 2001
PubMed
Summary

This study details the crystal structure of a new melaminium salt, bis(2,4,6-triamino-1,3,5-triazin-1-ium) sulfate dihydrate. The research reveals a 3D network formed by melaminium, sulfate, and water via hydrogen bonds.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A dark swelling in a hidden place.

Techniques in coloproctology·2020
Same author

Conformation of the azo bond and its influence on the molecular and crystal structures, IR and Raman spectra, and electron properties of 6-methyl-3,5-dinitro-2-[(E)-phenyldiazenyl]pyridine - Quantum chemical DFT calculations.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy·2017
Same author

Spectrally-resolved third-harmonic generation and the fundamental role of O-HCl hydrogen bonding in O<sub>h</sub>, T<sub>d</sub>-cobalt(ii) tetraphenylmethane-based coordination polymers.

Dalton transactions (Cambridge, England : 2003)·2017
Same author

Structure, vibrational spectra and DFT characterization of the intra- and inter-molecular interactions in 2-hydroxy-5-methylpyridine-3-carboxylic acid--normal modes of the eight-membered HB ring.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy·2013
Same author

Crystal and molecular structure of N-(4-nitrophenyl)-β-alanine--its vibrational spectra and theoretical calculations.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy·2010
Same author

Melaminium chloride hemihydrate.

Acta crystallographica. Section C, Crystal structure communications·2001

Area of Science:

  • Crystallography
  • Materials Science
  • Supramolecular Chemistry

Background:

  • Melaminium salts are nitrogen-rich compounds with potential applications in various fields.
  • Understanding the crystal structure of novel salts is crucial for predicting their properties.
  • Hydrogen bonding plays a key role in the self-assembly of crystalline materials.

Purpose of the Study:

  • To characterize the crystal structure of a newly synthesized melaminium salt.
  • To elucidate the role of hydrogen bonding in the formation of the crystal network.
  • To investigate the coordination environment of the sulfate anion within the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.

Related Experiment Videos

  • Analysis of bond lengths, angles, and intermolecular interactions (hydrogen bonds) was performed.
  • Geometric analysis of the sulfate anion's coordination sphere.

    • Main Results:

    • The crystal structure of bis(2,4,6-triamino-1,3,5-triazin-1-ium) sulfate dihydrate was successfully determined.
    • The structure consists of monoprotonated melaminium cations, sulfate anions, and water molecules.
    • A three-dimensional network is formed through extensive N-H···N and N-H···O hydrogen bonds between melaminium residues, sulfate ions, and water molecules.

    Conclusions:

    • The melaminium residues form 1D chains linked by N-H···N hydrogen bonds.
    • These chains are further interconnected by sulfate anions and water molecules, creating a robust 3D supramolecular network.
    • The study provides fundamental insights into the crystal engineering of melaminium-based materials.