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Updated: Aug 5, 2026

Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography
Published on: May 16, 2014
Highly diastereoselective reformatsky-type reaction promoted by tin iodide ate complex
Ikuya Shibata1, Toshihiro Suwa, Hideaki Sakakibara
1Department of Molecular Chemistry & Frontier Research Center, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. shibata@ap.chem.eng.osaka-u.ac.jp
Abstract:
[reaction: see text] An ate type of tin complex, Li(+)[n-Bu(2)SnI(3)](-)/HMPA, works as a novel type of reagent to accomplish the highly diastereoselective Reformatsky-type reaction by the halogen-metal exchange method.
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