Related Experiment Video
Updated: Jun 21, 2026

Clean Sampling and Analysis of River and Estuarine Waters for Trace Metal Studies
Published on: July 1, 2016
Determination of chromium in river waters by electrothermal atomic absorption spectrometry with preconcentration on a
1Department of Chemistry for Materials, Faculty of Engineering, Mie University, Tsu, Japan. nurul134@hotmail.com
Abstract:
The preconcentration of chromium on tantalum wire followed by electrothermal atomic absorption spectrometry with a tungsten tube atomizer is described. The preconcentration is accomplished by adsorbing chromium on a tantalum wire. The optimal immersion time was 3 mm. The best pH for chromium adsorption was 3. Under optimal conditions, the detection limit was 15 pg mU1 (3 x SIN). The effects on the preconcentration of chromium by large amounts of contaminants were evaluated. Even though matrix elements existed in 10(3)-10(4)-fold excess in water, the chromium absorption signal was not affected by the matrix elements. The method with preconcentration on tantalum wire was applied to the determination of chromium in river water.
More Related Videos
Related Concept Videos
Voltammetry: Stripping Methods
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
Precipitation Titration: Endpoint Detection Methods
In the Volhard method, a standard excess of AgNO3 is first added to the...
Precipitation Gravimetry
In determining nickel by gravimetric analysis, a precipitant of ethanolic dimethylglyoxime is added to a hot nickel salt solution. This is quickly followed by the dropwise addition of dilute ammonia solution until precipitation occurs. A...
Gas Chromatography: Types of Detectors-I
TCD is the earliest and most widely used detector that operates by measuring the changes in the thermal conductivity of the carrier gas. When a sample compound enters the detector,...
Atomic Absorption Spectroscopy: Lab
Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing nebulizer...

