[Synthesis of N-acetylglucosamine beta-aryl glycosides catalyzed by crown ethers]

V O Kur'ianov¹, T A Chupakhina, A E Zemliakov

¹Vernadsky Taurida National University, ul. Yaltinskaya 4, Simferopol, 95007 Ukraine.

|January 29, 2002

Abstract:

Glycosylation of phenols of various structure with alpha-D-glucosaminyl chloride peracetate in a solid phase-liquid system catalyzed by crown compounds was studied. The highest yields of aryl beta-glycosides were observed at room temperature in acetonitrile using anhydrous potassium carbonate as a base. The optimum phenol-glycosyl donor-base-crown ether ratio was 1:1:1:0.2.

Related Concept Videos

Articles linked to this work by shared authors, journal, and citation graph.

[Glycosilated derivatives of substituted hydroxylamine. II. Phase transfer synthesis and investigation of glycosyl transfer reaction of glucosaminides of substituted hydroxylavine].

Bioorganicheskaia khimiia·2014

[Features phase transfer catalytic glycosylation of aromatic hydroxy acids].

Bioorganicheskaia khimiia·2014

[Synthesis and antimicrobial ivestigation of 8-quinolinols glucosaminides].

Bioorganicheskaia khimiia·2012

[Synthesis of heteroaromatic N-beta-glycosides of N-acetylghicosamine under phase transfer conditions. III. 1,2,4-triazoIin-3-ones glucosaminides].

Bioorganicheskaia khimiia·2012

[Glycosides of hydroxylamine derivatives. I. phase transfer synthesis and study of isatine-3-oximes glucosaminides influence on bacterial luminescence].

Bioorganicheskaia khimiia·2011

[Synthesis of heteroaromatic N-beta-glycosides of N-acetylglucosamine under phase transfer conditions: II].

Bioorganicheskaia khimiia·2008

See all related articles

Related Experiment Videos

[Synthesis of N-acetylglucosamine beta-aryl glycosides catalyzed by crown ethers]

Related Concept Videos

[Glycosilated derivatives of substituted hydroxylamine. II. Phase transfer synthesis and investigation of glycosyl transfer reaction of glucosaminides of substituted hydroxylavine].

[Features phase transfer catalytic glycosylation of aromatic hydroxy acids].

[Synthesis and antimicrobial ivestigation of 8-quinolinols glucosaminides].

[Synthesis of heteroaromatic N-beta-glycosides of N-acetylghicosamine under phase transfer conditions. III. 1,2,4-triazoIin-3-ones glucosaminides].

[Glycosides of hydroxylamine derivatives. I. phase transfer synthesis and study of isatine-3-oximes glucosaminides influence on bacterial luminescence].

[Synthesis of heteroaromatic N-beta-glycosides of N-acetylglucosamine under phase transfer conditions: II].

[The Point Mutation in NOGGIN2 Protein That Enhances Its Ability to Bind Activin].

[The Cytoskelrtal Protein Zvxin Interacts with the Hedgehog Receptor Patched].

[Synthesis and Neurotropic Activity of 2,4-pyrano[4',3':4,5]pyrido[2,3-b]thieno[3,2-d] Pyrimidines].

[Inhibitory Properties of Nitrogen-Containing Adamantane Derivatives with Monoterpenoid Fragments Against Tyrosyl-DNA Phosphodiesterase I].

[Modulation of Ca(2+)-Dependent Proteiolysis under the Action of Weak Low-Frequency Magnetic Fields].

[Intracellular Protein Degradation in Growth of Atlantic Salmon, Salmo salar L].

Movement initiation-related signals differ across the caudal cingulate motor area, supplementary motor area, and primary motor cortex for contralateral but less so for ipsilateral movements in monkeys.

Location, Location, Location: Main Chain Poly(cobaltocenium)s Outperform Side Chain Analogues.

Conserved and rewired MAPK networks in human fungal pathogens.

Semicrystalline chain-growth photopolymer networks synthesized by orthogonal neat polymerization reactions.

Recent Advances in the Synthesis of Heterocycles via Diels-Alder Reactions on Chromone Cores.

Test substance preparation determines the tested fraction and the outcome of human health NAMs for poorly-water-soluble (pre)polymers.

Related Experiment Videos

[Synthesis of N-acetylglucosamine beta-aryl glycosides catalyzed by crown ethers]

Abstract:

Related Concept Videos

Related Articles