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Synthesis of the liposidomycin diazepanone nucleoside
Spencer Knapp1, Gregori J Morriello, George A Doss
1Department of Chemistry & Chemical Biology, Rutgers The State University of New Jersey, Piscataway, New Jersey 08854-8087, USA.
Organic Letters
|February 15, 2002
Abstract:
[structure: see text] The synthesis of the liposidomycin degradation product 4 from D-glucose establishes its stereochemistry as 5'S,6'S and, by incorporation of the earlier diazepanone relative stereochemical assignment, establishes the absolute stereochemistry of the liposidomycins 1 and 2 as 5'S,6'S,2'''S,3'''S.