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The crystal structure of human MRP14 (S100A9), a Ca(2+)-dependent regulator protein in inflammatory process

Hiroshi Itou1, Min Yao, Ikuko Fujita

  • 1Division of Biological Sciences, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan.

Insights

Human MRP14 (hMRP14), a calcium-binding protein, is crucial for myeloid cell functions during inflammation. Its crystal structure reveals a flexible C-terminal region and a potential target-binding site, offering insights into neutrophil adhesion.

Area of Science:

  • Biochemistry
  • Molecular Biology
  • Structural Biology

Background:

  • Human MRP14 (hMRP14) is a Ca(2+)-binding protein belonging to the S100 family.
  • It is co-expressed with human MRP8 (hMRP8) in myeloid cells and is vital for Ca(2+)-dependent inflammatory functions.
  • hMRP14, along with hMRP8, activates Mac-1, a beta(2) integrin essential for neutrophil adhesion to endothelial cells.

Purpose of the Study:

  • To determine the crystal structure of the holo form of human MRP14 (hMRP14).
  • To investigate the binding interactions and structural characteristics of hMRP14.
  • To compare the structure of hMRP14 with homologous proteins (hMRP8, hS100A12) and discuss the functional implications.

Main Methods:

  • X-ray crystallography was used to analyze the crystal structure of hMRP14 at 2.1 Å resolution.
  • Structural comparisons were made between hMRP14, hMRP8, and human S100A12.
  • Analysis of the binding of Chaps molecules to the hinge region of hMRP14.

Main Results:

  • The crystal structure of holo hMRP14 was determined at 2.1 Å resolution.
  • hMRP14 possesses a distinctively long and flexible C-terminal region compared to other S100 proteins.
  • Chaps molecules were observed to bind to the hinge region connecting the EF-hand motifs, indicating a potential target-binding site.

Conclusions:

  • The flexible C-terminal region of hMRP14 may play a significant functional role.
  • The identified binding site suggests a mechanism for target interaction in hMRP14 function.
  • Structural insights into hMRP14 provide a basis for understanding the MRP8/14 hetero-complex and its role in inflammation and neutrophil adhesion.

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