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Updated: Aug 3, 2026

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
Published on: April 1, 2013
Synthetic applications of electrophilic fluorodesilylation
Véronique Gouverneur1, Benjamin Greedy
1University of Oxford, The Dyson Perrins Laboratory South Parks Road, OX1 3QY Oxford, UK. veronique.gouverneur@chem.ox.ac.uk
Abstract:
Recently, with the appearance of electrophilic sources of fluorine including the commercially available N-F reagents, the concept of electrophilic fluorodesilylation has emerged as a new strategy to prepare a variety of fluorine containing compounds. This paper highlights how this concept has been applied to the preparation of a series of fluorinated molecules including fluoroaromatic compounds, fluoroalkenes, difluoroamides, difluoroalcohols, difluoroethers and alpha-fluorinated carbonyl derivatives.
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