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Adsorption of colloidal particles on a charged surface: cluster Monte Carlo simulations
Takamichi Terao1, Tsuneyoshi Nakayama
1Department of Applied Physics, Hokkaido University, Sapporo 060-8628, Japan.
Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|February 28, 2002
Abstract:
We investigate the adsorption of colloidal particles on a charged surface by the cluster Monte Carlo simulation. Under the primitive model of asymmetric electrolytes, the density profiles of colloidal particles at a surface are analyzed as a function of the electrostatic coupling parameter. In the strong coupling regime numerical results show the like-charged adsorption between colloidal particles and a charged surface, which cannot be explained by the Derjaguin-Landau-Verwey-Overbeek theory.