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Comment on mu(1,3)-azido-diazidotetrakis(1,10-phenanthroline)dicopper(II) azide tetrahydrate

Ponraj Prabakaran1

  • 1RIKEN Tsukuba Institute, 3-1-1 Koyadai, Ibaraki 305-0074, Japan. praba@rtc.riken.go.jp

Acta Crystallographica. Section C, Crystal Structure Communications
|April 5, 2002
PubMed

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.