Related Experiment Video
Updated: Oct 1, 2026

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
Temperature difference between bulk and surface transition in freely suspended smectic films
D Schlauf1, C Bahr, M Glogarová
1Institute of Physical Chemistry, University Marburg, D-35032 Marburg, Germany.
Abstract:
We report an ellipsometric study of freely suspended films of a chiral liquid-crystal compound possessing the phase sequence smectic-C-smectic-A-isotropic with a very broad (67 K) smectic-A phase range. We observe a smectic-C-smectic-A surface transition which is situated more than 60 K above the bulk smectic-C-smectic-A transition temperature. Possible reasons for this unusually large temperature shift are discussed.
Related Concept Videos
Surface Tension
Boundary Conditions for Current Density
Magnetostatic Boundary Conditions
Surface Tension and Surface Energy
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
Phase Transitions: Sublimation and Deposition
Electrostatic Boundary Conditions in Dielectrics
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity.

