Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Reversible polymerizations and aggregations.

Sandra C Greer1

  • 1Department of Chemical Engineering, The University of Maryland, College Park, College Park, Maryland 20742-2111, USA. sg28@umail.umd.edu

Annual Review of Physical Chemistry
|April 25, 2002
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Anneke Levelt Sengers: An international authority in the thermodynamics of fluids and a passionate advocate for women in science.

Proceedings of the National Academy of Sciences of the United States of America·2024
Same author

Erratum: "The polymerization of actin: Structural changes from small-angle neutron scattering" [J. Chem. Phys. 123, 154904 (2005)].

The Journal of chemical physics·2016
Same author

Self-assembly of the triblock copolymer 17R4 poly(propylene oxide)₁₄-poly(ethylene oxide)₂₄-poly(propylene oxide)₁₄ in D₂O.

Journal of colloid and interface science·2014
Same author

Micelles of polybutadiene-b-poly(ethylene oxide) in deuterated methanol and deuterated cyclohexane.

Journal of colloid and interface science·2012
Same author

Micellization and phase separation for triblock copolymer 17R4 in H2O and in D2O.

Langmuir : the ACS journal of surfaces and colloids·2011
Same author

Micelles of polybutadiene-b-poly(ethylene oxide) in methanol, cyclohexane, and methanol + cyclohexane.

Langmuir : the ACS journal of surfaces and colloids·2009
Same journal

Coadsorption of Atmospheric Surface-Active Organics at the Aqueous Interface: A Molecular Dynamics Study.

Annual review of physical chemistry·2026
Same journal

Control of Chemical Reactions in Radiofrequency Ion Traps.

Annual review of physical chemistry·2026
Same journal

Theories of Chiral-Induced Spin Selectivity: A Pedagogical Overview.

Annual review of physical chemistry·2026
Same journal

Quantum Computing Beyond Ground-State Electronic Structure: A Review of Progress Toward Quantum Chemistry Out of the Ground State.

Annual review of physical chemistry·2026
Same journal

First-Principles Simulations of Chemical Transformations in Nanoporous Materials and Industrial Catalysts.

Annual review of physical chemistry·2026
Same journal

Structure and Dynamics of Microhydrated Complexes Revealed with Rotational Spectroscopy.

Annual review of physical chemistry·2026
See all related articles

Reversible polymer aggregation, like phase transitions, depends on temperature and composition. This study explores the physical chemistry of three systems: alpha-methylstyrene, sulfur, and actin.

Area of Science:

  • Physical Chemistry
  • Polymer Science
  • Materials Science

Background:

  • Monomer aggregation into polymers can be reversible.
  • Reversible aggregation shares similar signs for entropy and enthalpy.
  • This behavior resembles a phase transition.

Purpose of the Study:

  • To explore the physical chemistry of reversible monomer-polymer aggregation.
  • To compare theories and experiments for selected systems.
  • To identify open questions in the field.

Main Methods:

  • Comparative analysis of existing theories.
  • Review of experimental data.
  • Focus on three distinct systems: alpha-methylstyrene, sulfur, and actin.

Related Experiment Videos

Main Results:

  • Reversible aggregation is governed by thermodynamic variables like temperature and composition.
  • Observed similarities in aggregation behavior across organic, inorganic, and biological systems.
  • Identified discrepancies between theoretical predictions and experimental findings.

Conclusions:

  • Reversible polymerizations exhibit phase-transition-like characteristics.
  • Further theoretical and experimental work is needed to fully understand these systems.
  • Understanding these systems has implications for materials science and biophysics.