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Synthesis of 1,1'-binaphthyl-based enantiopure C(60) dimers
Francesco Giacalone1, José L Segura, Nazario Martín
1Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense, E-28040-Madrid, Spain.
The Journal of Organic Chemistry
|May 11, 2002
Abstract:
The first enantiomerically pure and soluble C(60) dimers have been synthesized from suitably functionalized 1,1'-binaphthyl derivatives by 1,3-dipolar cycloaddition of the respective in situ generated diazo compounds to C(60). These systems exhibit optical and electrochemical activity.