Orientational distributions in smectic liquid crystals showing V-shaped switching investigated by polarized Raman...

Molecular orientational order parameters have been obtained by Raman scattering in two types of liquid crystal materials showing the V-shaped switching in thin homogeneous cells. One is the Mitsui mixture and the other is one component of the Inui mixture. The antiferroelectric phase exists in the bulk of both materials but, in thin homogeneous cells, the stability is distinct from each other. The obtained distribution of the local in-plane directors at the tip of the V is considerably broad in the former, while it is narrow in the latter. These differences have been explained by the barrier between the ferroelectric and antiferroelectric orderings, the chiral twisting power, and the interface induced destruction of the antiferroelectric ordering.