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Stereochemical study of phosphonothioate cleavage by a metallomicelle
Robert A Moss1, Paul K Gong, Hugo Morales-Rojas
1Department of Chemistry, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA. moss@rutchem.rutgers.edu
Organic Letters
|May 25, 2002
Abstract:
[reaction: see text] The copper metallomicellar hydrolysis of O-methyl O-4-nitrophenyl phenylphosphonothioate to O-methyl phenylphosphonothioic acid takes place with effectively complete inversion at phosphorus.