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Related Experiment Videos

[The conversion from CS2 to COS by spark discharge].

Bin Sun1, Xunxi Pan, Jian Hou

  • 1Institute of Environmental Science, Fudan University, Shanghai 200433, China.

Huan Jing Ke Xue= Huanjing Kexue
|June 7, 2002
PubMed
Summary

Lightning can convert carbon disulfide (CS2) to carbonyl sulfide (COS) in the atmosphere. This study simulated lightning conditions, revealing factors influencing COS production during thunderstorms.

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Area of Science:

  • Atmospheric Chemistry
  • Plasma Chemistry

Context:

  • Carbon disulfide (CS2) is a volatile compound with potential atmospheric relevance.
  • Lightning is a significant atmospheric phenomenon with complex chemical reactions.
  • Understanding the conversion of CS2 to COS is crucial for atmospheric modeling.

Purpose:

  • To investigate the conversion of carbon disulfide (CS2) to carbonyl sulfide (COS) under simulated lightning conditions.
  • To identify key factors influencing the formation of COS during electric discharge.
  • To propose potential mechanisms for CS2 to COS conversion in atmospheric environments.

Summary:

  • Simulated lightning (spark discharge) experiments showed that CS2 reacts with atmospheric O2 and H2O at 1.33 x 10(3) Pa CS2, 10(5) Pa total pressure, and 25°C.

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  • Carbonyl sulfide (COS) was produced alongside CO, CO2, and SO2.
  • CS2 concentration, water vapor presence, and discharge duration significantly impacted COS yield.
  • Impact:

    • Provides evidence for lightning-induced conversion of CS2 to COS in thunderstorms.
    • Contributes to a better understanding of atmospheric sulfur cycling.
    • Informs atmospheric chemistry models regarding trace gas formation during electrical events.