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Cycloaddition reactions of dihapto-coordinated furans

Lee A Friedman1, Michal Sabat, W Dean Harman

  • 1Department of Chemistry, University of Virginia, Charlottesville, Virginia 22901, USA.

Journal of the American Chemical Society
|June 20, 2002
PubMed
Summary

Rhenium complexes with furan ligands undergo cycloaddition reactions with TCNE and DMAD, forming novel oxabicycloheptene and oxabicyclo[3.2.0]heptadiene structures. These reactions yield valuable intermediates for oxepin synthesis.

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