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Carbon dioxide as a solubility "switch" for the reversible dissolution of highly fluorinated complexes and reagents

Philip G Jessop1, Marilyn M Olmstead, Christopher D Ablan

  • 1Department of Chemistry, University of California, Davis, California 95616-5295, USA. jessop@chem.ucdavis.edu

Inorganic Chemistry
|June 25, 2002
PubMed

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As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
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