Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Heterogeneous C-C coupling and polymerization catalysts prepared by ROMP.

Michael R Buchmeiser1

  • 1Institute of Analytical Chemistry and Radiochemistry, University of Innsbruck, Innrain 52 a, Austria. michael.r.buchmeiser@uibk.ac.at

Bioorganic & Medicinal Chemistry Letters
|June 28, 2002
PubMed
Summary

This study details catalytic supports made using ring-opening metathesis polymerization (ROMP). These supports are effective for palladium-catalyzed coupling reactions and ruthenium-catalyzed olefin metathesis.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Enhanced Aging Stability of Ordered Mesoporous Silica Materials Synthesized via True Liquid Crystal Templating-A Small-Angle X-Ray Scattering Study.

Materials (Basel, Switzerland)·2026
Same author

Relevant Metal Oxidation States of MAO-Activated Chromium Catalysts for Ethylene Oligomerization.

Inorganic chemistry·2026
Same author

Tuning Regioselectivity in Cyclopolymerization through Carbene Ligand Size Modulation in Molybdenum Imido Alkylidene Catalysts.

Macromolecules·2026
Same author

Ring-Expansion Metathesis Polymerization under Confinement.

Journal of the American Chemical Society·2025
Same author

Meltblow Processing of Poly (Ethylene Furanoate)-Bio-Based Polyester Nonwovens.

Materials (Basel, Switzerland)·2025
Same author

Room Temperature Ethene to Propene (ETP) Tandem Catalysis using Single Crystalline Solid-State Molecular Pre-Catalysts.

Angewandte Chemie (International ed. in English)·2025

Area of Science:

  • Catalysis
  • Polymer Chemistry
  • Materials Science

Background:

  • Heterogeneous catalysts offer advantages in separation and reusability.
  • Ring-opening metathesis polymerization (ROMP) provides a versatile route to functional polymers.
  • Developing robust catalytic supports is crucial for efficient chemical transformations.

Purpose of the Study:

  • To review recent advancements in catalytic supports synthesized via ROMP.
  • To highlight the application of these supports in key catalytic reactions.
  • To outline the general synthetic strategies for creating these ROMP-derived supports.

Main Methods:

  • Synthesis of polymeric supports using ROMP.
  • Immobilization of catalytically active metal centers (e.g., Pd, Ru).

Related Experiment Videos

  • Characterization of the resulting heterogeneous catalytic systems.

    • Main Results:

    • Demonstrated efficacy of ROMP-based supports in palladium-catalyzed C-C coupling reactions (Heck, Sonogashira-Hagihara, Suzuki).
    • Successful application of these supports in ruthenium-catalyzed olefin metathesis.
    • Established a general synthetic concept for preparing these advanced catalytic materials.

    Conclusions:

    • ROMP is a powerful technique for creating versatile heterogeneous catalytic supports.
    • These supports enable efficient and selective performance in important cross-coupling and metathesis reactions.
    • The outlined synthetic approaches facilitate the development of next-generation catalytic systems.