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Total synthesis of caerulomycin C via the halogen dance reaction
Tarek Sammakia1, Eric L Stangeland, Mark C Whitcomb
1Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, USA. sammakia@colorado.edu
Organic Letters
|July 6, 2002
Abstract:
[reaction: see text] The total synthesis of caerulomycin C is described. Key steps in this synthesis utilize 1,2-, 1,3-, and 1,4-halogen dance reactions for the functionalization of the pyridine ring.