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[Perspective oxide materials for anode of low-temperature electrochemical oxygen regeneration system]

Aviakosmicheskaia I Ekologicheskaia Meditsina = Aerospace and Environmental Medicine

|July 9, 2002

Abstract:

The paper summarizes results of substantiating, selecting, developing, manufacturing and testing of oxidic multicomponent surface compositions with the perovskite structure on porous titanium matrixes proposed for use in anodes of low-temperature electrochemical systems with a liquid electrolyte. Electrochemical activity of 88 oxide layers was evaluated as a function of composition, concentration and temperature of the carbonate electrolyte, elementary content of oxidic composition, and physical/chemical characteristics of the crystal structure. It was shown that the electrode process can be controlled by changing components of the electrolyte or complexity of the multicomponent oxidic surface compositions.

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Types of Reversible Electrodes

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For electrode reversibility to be maintained, all the reactants and products involved in the half-reaction must be present at the electrode. There are several types of reversible electrodes (half-cells).In metal-metal-ion electrodes, a metal balances electrochemically with a solution of its own ions. Examples are Cu2+|Cu and Zn2+|Zn. Metals that react with the solvent, like group 1 and most group 2 metals, which react with water, and zinc, which reacts with aqueous acidic solutions, cannot be...

Articles linked to this work by shared authors, journal, and citation graph.

[Some aspects of water electrolysis with the use of a solid polymer electrolyte].

Aviakosmicheskaia i ekologicheskaia meditsina = Aerospace and environmental medicine·2007

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Aviakosmicheskaia i ekologicheskaia meditsina = Aerospace and environmental medicine·2003

[Thermodynamics of the state of a multicomponent CO2-CO-H2O-H2-N2 gas mixture in an electrolyzer with a solid electrolyte].

Kosmicheskaia biologiia i aviakosmicheskaia meditsina·1987

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Kosmicheskaia biologiia i aviakosmicheskaia meditsina·1986

[Experimental research on the process of decomposition of a CO2-CO-H2O-H2-N2 gas mixture in an electrolytic cell with a solid electrolyte].

Kosmicheskaia biologiia i aviakosmicheskaia meditsina·1986

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