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Rapid parallel synthesis of combinatorial libraries of substituted 3-thio-1,2,4-triazoles and 2-thioimidazoles

Maria-Elena Theoclitou1, Nancy G J Delaet, Leslie A Robinson

  • 1Bristol-Myers Squibb, Pharma Research Laboratories, 4570 Executive Drive, San Diego, California 92121, USA. Maria-Elena.Thouclitou@dupontpharma

Journal of Combinatorial Chemistry
|July 9, 2002
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.