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Synthesis and characterisation of the first carbene and diazabutadiene-indium(II) complexes
Robert J Baker1, Robert D Farley, Cameron Jones
1Department of Chemistry, University of Wales, Cardiff, P.O. Box 912, Park Place, Cardiff, UK CF10 3TB.
Chemical Communications (Cambridge, England)
|July 12, 2002
Abstract:
The reactions of IMes [:CN(Mes)C2H2N(Mes), Mes = mesityl] and DAB [(ArN=CH)2, Ar = C6H3Pri2-2,6] with indium(I) halides have afforded the first carbene and diazabutadiene indium(II) complexes, [In2Br4(IMes)2] and [In2Cl2(DAB.)2], both of which have been crystallographically characterised.