Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Hexa(2-pyridyl)[3]radialene: self-assembly of a hexanuclear silver array.

Peter J Steel1, Christopher J Sumby

  • 1Chemistry Department, University of Canterbury, Christchurch, New Zealand. p.steel@chem.canterbury.ac.nz

Chemical Communications (Cambridge, England)
|July 18, 2002
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Biomimetic Synthesis of Seven Halenaquinone Meroterpenoids.

Journal of the American Chemical Society·2026
Same author

Dual Metalation Site Zr-Metal-Organic Frameworks: Controlled Synthesis of Metal-Organic Framework-Bound Proximal Metal Complexes.

Inorganic chemistry·2026
Same author

Two different products from the reaction between 2-formylphenylboronic acid and benzhydrazide: benzoyl hydrazone versus dimer.

Acta crystallographica. Section C, Structural chemistry·2026
Same author

Rhodium Carbonyl Complexes within the Tunable Microenvironments of UiO-66 Analogues.

Inorganic chemistry·2025
Same author

UCNP@ZnO:Co/Ag Composites: A Dual-Action Platform for Antibacterial Photodynamic Therapy via Synergistic Silver Ion and Reactive Oxygen Species Release.

ACS applied materials & interfaces·2025
Same author

Understanding the Role of the Zr-MOF Support Structure on Templated Ternary CO<sub>2</sub> Hydrogenation Catalyst Structure and Activity.

ACS applied materials & interfaces·2025

A novel hexa(2-pyridyl)[3]radialene ligand reacted with silver tetrafluoroborate to form a M6L2 cage. This cage structure successfully encapsulated a mu 3-fluorido anion.

Area of Science:

  • Coordination Chemistry
  • Supramolecular Chemistry
  • Organometallic Chemistry

Background:

  • The synthesis of novel ligands is crucial for developing new coordination complexes.
  • Radialene ligands offer unique structural and electronic properties for metal complexation.
  • Encapsulation of small anions within supramolecular cages remains a significant challenge.

Purpose of the Study:

  • To synthesize and characterize a new supramolecular cage using a novel hexa(2-pyridyl)[3]radialene ligand.
  • To investigate the coordination behavior of the hexa(2-pyridyl)[3]radialene ligand with silver ions.
  • To determine if the resulting cage structure can encapsulate a fluorido anion.

Main Methods:

  • Synthesis of the hexa(2-pyridyl)[3]radialene ligand.

Related Experiment Videos

  • Reaction of the ligand with silver tetrafluoroborate under specific conditions.
  • X-ray crystallography for structural elucidation of the M6L2 cage.
  • Spectroscopic methods for characterization.

    • Main Results:

    • Formation of a discrete M6L2 cage complex.
    • The cage structure was confirmed to encapsulate a single mu 3-fluorido anion.
    • Structural analysis revealed the coordination mode of the radialene ligand around the silver centers.

    Conclusions:

    • The hexa(2-pyridyl)[3]radialene ligand is effective in constructing M6L2 supramolecular cages.
    • The M6L2 cage demonstrates the ability to encapsulate a fluorido anion.
    • This work expands the scope of ligand design for anion encapsulation in coordination chemistry.