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Toward constructing nanoscale hydroxo-lanthanide clusters: syntheses and characterizations of novel tetradecanuclear
Ruiyao Wang1, Datong Song, Suning Wang
1Department of Chemistry, Queen's University, Kingston, Ontario K7L 3N6, Canada. wangs@chem.queensu.ca
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
Two novel tetradecanuclear hydroxo-lanthanide complexes, formulated as Ln14(mu 4-OH)2(mu 3-OH)16(mu-eta 2-acac)8(eta 2-acac)16, Ln = Tb, 1; Eu, 2; acac = acetylacetonato, were synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and phosphorescence spectroscopy.