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Novel catalysis of dendrimer-bound Pd(0) complexes: sterically steered allylic amination and the first application
Tomoo Mizugaki1, Makoto Murata, Masahiko Ooe
1Department of Chemical Science and Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
Phosphinated dendrimer-bound Pd(0) complex catalysts show high stereoselectivity for allylic amination due to the surface congestion of dendrimers and can be easily recycled without loss of activity under thermomorphic conditions.