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Discriminating between lanthanide ions: self-assembly of heterodimetallic triple-stranded helicates
Nicolas André1, Rosario Scopelliti, Gérard Hopfgartner
1Institute of Molecular and Biological Chemistry, BCH, Swiss Federal Institute of Technology, CH-1015-Lausanne, Switzerland.
Abstract:
A bis-terdentate segmental ligand has been designed which self-assembles with lanthanide ions of different size to yield heterodimetallic triple-stranded helicates.