Related Experiment Video
Updated: Sep 30, 2026

06:53
Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Molecular batteries: synthesis and characterization of a dendritic 19-electron FeI complex that reduces C60 to its
Jamie Ruiz1, Charlotte Pradet, François Varret
1Groupe de Chimie Supramoléculaire des Métaux de Transition, LCOO, UMR CNRS No 5802, Université Bordeaux I, 33405 Talence Cedex, France.
Abstract:
Both redox forms of the dendrimer [dendr-64-NHCOCpFeII(eta 6-C6Me6)]64+/0, 6/7, are synthesized and characterized, and the 19-electron form reduces C60 to [dendr-64-NHCOCpFeII(eta 6-C6Me6)]64+(C60-.)64, 8.

