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Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes
Silvio Aime1, Alessandro Barge, Andrei S Batsanov
1Dipartimento di Chimica IFM, Università di Torino, Via P. Giuria I-10125, Torino, Italy.
Chemical Communications (Cambridge, England)
|July 19, 2002
Abstract:
The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.