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A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions
Jun Tao1, Yong Zhang, Ming-Liang Tong
1School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275, China.
Chemical Communications (Cambridge, England)
|July 20, 2002
Abstract:
A novel coordination polymer of mixed-valence copper(I,II) with 4,4'-bipyridine and in situ oxidized isophthalate, [Cu2(ipO)(4,4'-bpy)] (ipOH = 2-hydroxyisophthalate), was hydrothermally synthesized and crystallographically characterized to be a laminated structure via weak copper(II)--oxygen interactions.