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Updated: Jul 12, 2026

Setting Limits on Supersymmetry Using Simplified Models
Published on: November 15, 2013
Is the axial zero-field splitting parameter of tetragonally elongated high-spin manganese(III) complexes always
Susanne Mossin1, Høgni Weihe, Anne-Laure Barra
1Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark.
Abstract:
The positive axial zero-field splitting parameter D relevant for the S = 2 ground state of [Mn(cyclam)I2]I (cyclam = 1,4,8,11-tetraazacyclotetradecane) is interpreted using the valence bond configuration interaction model which explicitly considers the covalency of the manganese-iodide bond.
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