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Benzyl anion abstraction from a (beta-diiminato)Fe(II) benzyl complex
Timo J J Sciarone1, Auke Meetsma, Bart Hesssen
1Dutch Polymer Institute/Center for Catalytic Olefin Polymerization, Stratingh Institute for Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
Chemical Communications (Cambridge, England)
|August 13, 2002
Abstract:
The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)-Fe(CH2Ph)] reacts with B(C6F5)3 to yield a paramagnetic contact ion pair with an eta 2-(o,m)-[PhCH2B(C6F5)3] anion, which was characterised by X-ray diffraction.