Related Experiment Videos
Silicon-tethered cyclocarbonylation of alkynes
Anthony J Pearson1, Jin Bum Kim
1Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, USA. ajp4@po.cwru.edu
Organic Letters
|August 17, 2002
Abstract:
[reaction: see text] Temporary union of alkynes in the Fe(CO)5-promoted cyclocarbonylation provides a method for carbonylative cross-coupling of alkynes to construct unsymmetrically substituted cyclopentadienones.