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Concise total synthesis of (+/-)-aloperine and 6-epi-aloperine
Daniele Passarella1, Marco Angoli, Alessandra Giardini
1Dipartimento di Chimica Organica e Industriale, Università degli Studi di Milano, Via Venezian 21, 20133 Milano, Italy. Daniele.Passarella@unimi.it
Organic Letters
|August 17, 2002
Abstract:
[reaction: see text] Total synthesis of aloperine and 6-epi-aloperine is reported. The crucial steps of the synthetic strategy are an aza-annulation reaction and an intermolecular Diels-Alder reaction. The synthetic plan proceeds from commercially available piperidine-2-ethanol.