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Enzyme-catalysed oxygenation and deoxygenation routes to chiral thiosulfinates

Derek R Boyd¹, Narain D Sharma, Martina A Kennedy

¹School of Chemistry, Queen's University of Belfast, Belfast, UK BT9 5AG.

Chemical Communications (Cambridge, England)

|August 23, 2002

Abstract:

Enantioenriched thiosulfinates have been obtained by dioxygenase- and chloroperoxidase-catalysed oxidation of 1,2-disulfides and dimethyl sulfoxide reductase-catalysed deoxygenation.

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