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Structure and reactivity of a novel parallel thiosulfito (SSO2-S:S') rhodium dinuclear complex
Kimie Shiomi1, Brian K Breedlove, Hiroaki Kitayama
1Department of Material Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Chemical Communications (Cambridge, England)
|August 29, 2002
Abstract:
The parallel thiosulfite ligand (SSO2) in a rhodium complex, which is formed by oxygenation of a bridging disulfide, is converted to a bridging hydrocarbyl thiolate ligand and sulfur dioxide gas by the reaction with hydrocarbyl halides.