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Hydrothermal synthesis of the first vanadomolybdenum polyoxocation with a "metal-bonded" spherical framework
Wenbin Yang1, Canzhong Lu, Xiaoping Zhan
1The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China.
Inorganic Chemistry
|September 11, 2002
Abstract:
The heteropoly compound [(V(V)O(4))Mo(VI)(12)O(36)(V(IV)O)(6)][(OH)(9)].11H(2)O (1), synthesized by hydrothermal method under weak basic conditions, represents the first mixed Mo/V six-capped Keggin structural derivative with a spherical skeleton, and the first transition metal polyoxocation. The successful synthesis of 1 demonstrates that basic hydrothermal synthesis might be a power synthetic route to the isolation of more new polycationic metal-oxo clusters.