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H(2)O(2) in CO(2): sustainable production and green reactions
Dan Hâncu1, Jordan Green, Eric J Beckman
1Chemical Engineering Department, Benedum Hall 1249, University of Pittsburgh, Pittsburgh, Pennsylvania 15261, USA. danhancu@lyondell.com
Accounts of Chemical Research
|September 18, 2002
Abstract:
Hydrogen peroxide is a "green" oxidant whose relatively high cost has prevented it from being applied to commodity chemical processing. Interestingly, those attributes of the current H(2)O(2) process that contribute to the high cost also contribute to its nonsustainable features. We have consequently explored the generation of hydrogen peroxide both by the AQ route and directly from hydrogen and oxygen using liquid CO(2) as the solvent, because CO(2) provides some unique advantages to H(2)O(2) synthesis.