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Updated: Sep 21, 2026

Synthesis of Zeolites Using the ADOR (Assembly-Disassembly-Organization-Reassembly) Route
Published on: April 3, 2016
First molecular switch encapsulated within the cavities of a zeolite. A dramatic lifetime increase of the
M Alvaro1, M N Chretien, B Ferrer
1Instituto de Tecnología Química CSIC-UPV, Departamento de Química UPV, Avda de los Naranjos s/n 46022, Valencia, Spain.
Abstract:
A [2]-catenane consisting of a bipyridinium cyclophane and a dioxybenzene macrocyclic polyether has been encapsulated within the supercages of zeolite Y by ship-in-a-bottle synthesis; laser flash photolysis reveals that the charge-separated species decays in hundreds of microseconds in contrast to the few picoseconds previously reported for the same transient in acetonitrile.
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