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Updated: Jul 28, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

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Published on: April 4, 2014

Palladium-catalysed cross-coupling reactions in supercritical carbon dioxide

T R Early1, R S Gordon, M A Carroll

  • 1Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Pembroke Street, Cambridge, UK CB2 3RA.

Chemical Communications (Cambridge, England)
|September 21, 2002
PubMed
Summary

Heck and Suzuki reactions were successfully performed in supercritical carbon dioxide, achieving good yields. This green chemistry approach utilizes palladium acetate and tri-tert-butylphosphine with various substrates.

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