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Direct in situ observation of increasing structural dimensionality during the hydrothermal formation of
Chemical Communications (Cambridge, England)
|September 21, 2002
Abstract:
The first time-resolved in situ X-ray diffraction studies of the hydrothermal crystallisation of open-framework zinc phosphates reveal a pathway of sequential crystallisation involving formation of a metastable low dimensional chain phase before the growth of three-dimensional zeolitic architectures.