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Tandem anionic Michael addition/radical cyclizations: a new and efficient strategy for the synthesis of
1Institut für Organische Chemie, TU Braunschweig, Hagenring 30 D-38106, Braunschweig, Germany. u.jahn@tu-bs.de
Chemical Communications (Cambridge, England)
|September 21, 2002
Abstract:
The combination of anionic Michael addition of lithium ester enolates with radical 5-exo cyclizations through SET oxidation gives highly functionalized cyclopentanes.