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Novel self-assembled monolayers of disulfides with bicyclo[2.2.2]octane moieties of Au(111)

S Fujii1, U Akiba, M Fujihira

  • 1Department of Biomolecular Engineering, Tokyo Institute of Technology, 4259 Nagatsuta Midori-ku, Yokohama, 226-8501, Japan.

Chemical Communications (Cambridge, England)
|September 21, 2002
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.