Related Experiment Videos
Inhibition and acceleration of deuterium exchange in amide-functionalized monolayer-protected gold clusters
Cheryl Briggs1, Tyler B Norsten, Vincent M Rotello
1Department of Chemistry, University of Massachusetts, Amherst, MA 01003, USA.
Chemical Communications (Cambridge, England)
|September 26, 2002
Abstract:
Hydrogen/deuterium exchange rates in amide-functionalized monolayer protected gold clusters (MPCs) are controlled by the radial nature of the surface, with inhibition and catalysis observed at different chain lengths.