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Self-assembly luminescent heteroheptanuclear complexes with metal diphosphine and metal thiolate as components
Hong-Wu Xu1, Zhong-Ning Chen, Shoji Ishizaka
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 35002, China.
Chemical Communications (Cambridge, England)
|September 26, 2002
Abstract:
Self-assembly between the building blocks [M2(mu-dppm)2(MeCN)2]2+ (M = Cu or Ag; dppm = bis(diphenylphosphino)methane) and M'(aet)2 (aet = 2-aminoethanethiolate) afforded luminescent heterohepta-nuclear complexes [Cu4M'3(mu-dppm)3(mu 3-aet)4(mu-aet)2]4+ (M' = Ni 1; Pd 2) or heterotrinuclear complexes [Ag2M'(mu-dppm)2(mu-aet)2]2+ (M' = Ni 3, Pd 4).