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One pot/two donors/one diol give one differentiated trisaccharide: powerful evidence for reciprocal donor-acceptor
Bert Fraser-Reid1, J Cristóbal López, K V Radhakrishnan
1Natural Products and Glycotechnology Research Institute Inc, (NPG), 4118 Swarthmore Road, Durham, North Carolina 27706, USA. Dglucose@aol.com
Chemical Communications (Cambridge, England)
|October 3, 2002
Abstract:
Three component, one-pot reactions involving equimolar amounts of the acceptor diol and both armed and disarmed donors presented simultaneously, produce a single double-differential glycosidation product; this phenomenon provides evidence for Reciprocal Donor Acceptor Selectivity (RDAS).