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A coordination network containing metal-organometallic secondary building units based on pi-bonded benzoquinone
Moonhyun Oh1, Gene B Carpenter, Dwight A Sweigart
1Department of Chemistry, Brown University, Providence, Rhode Island 02912, USA.
Chemical Communications (Cambridge, England)
|October 3, 2002
Abstract:
In DMSO-MeOH solvent the complex [(eta 4-benzoquinone)Mn(CO)3]- (QMTC) reacts with Mn2+ ions to produce the coordination polymer (Mn2[(eta 4-benzoquinone)Mn(CO)3]4(DMSO))n, which consists of dimanganese secondary building units interconnected by QMTC spacers.