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[Fe2(C10O8H2)]: an antiferromagnetic 3D iron(II) carboxylate built from ferromagnetic edge-sharing octahedral chains
M Sanselme1, J M Grenèche, M Riou-Cavellec
1Institut Lavoisier (UMR CNRS 8637), 45 avenue des Etats-Unis, 78035, Versailles, France.
Chemical Communications (Cambridge, England)
|October 3, 2002
Abstract:
The first three-dimensional iron(II) tetracarboxylate is built from the connection of chains of edge-sharing Fe(II) octahedra by 1,2,4,5-benzenetetracarboxylates; magnetic measurements show an antiferromagnetic coupling of ferromagnetic chains below TN = 25(1) K.