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First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework
1Department of Chemistry, Fuzhou University, wFuzhou 350002, P. R. China. bzlin@hqu.edu.cn
Chemical Communications (Cambridge, England)
|October 5, 2002
Abstract:
The hydrothermal reaction of V2O5, Cu(CH3COO)2.H2O, 1,2-diaminopropane and [N(CH3)4]OH yields the novel three-dimensional open-framework solid [(Cu(1,2-pn)2)7-(V16O38(H2O))2].4H2O constructed from the new mixed-valence [V16O38(H2O)]7- clusters interconnected through mu 2-[Cu(1,2-pn)2]2+ groups.