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Updated: Jul 31, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Raman and infrared study of the crystals with molecular anions in the region of a solid-liquid phase transition
M M Gafurov1, A R Aliev, I R Akhmedov
1Daghestan Scientific Center, Institute of Physics, Russian Academy of Sciences, Makhachkala.
Abstract:
It is presented the Raman and infrared (IR) spectroscopic investigations of the thiocyanates: LiSCN, NaSCN, KSCN, RbSCN, CsSCN; nitrates: Ca(NO3)2, Sr(NO3)2, Ba(NO3)2, Pb(NO3)2; and perrhenates: LiReO4, NaReO4, KReO4 in the region of a solid-liquid phase transition. The differences in a pre-melting behavior of this salts were found which can be attributed to a different geometry of the SCN-, NO3- and ReO4- anions.
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